The Salvation Army takes donations of clothing and home goods plus furniture. They re-sell these items in their thrift stores across America at a good value.
The Society of St. Vincent de Paul helps the poor with needs, especially clothing.
National Council of the United States
Society of St. Vincent de Paul
58 Progress Parkway
St. Louis, MO 63043-3706
Catholic Social Services are active in many local communities. Contact your local diocese or look in the yellow pages for their information.
These are just a few of the ways you can help to fulfill this work of mercy. Don't throw out those clothes..give them away.
Please visit your local pregnancy center and woman's shelter to see if they will take donations of gently used baby clothing and business attire for women trying to re-enter the workforce.